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91.
92.
We focus on the distribution and free energy of a wormlike polymer confined between two parallel hard walls.The variation in the distribution and free energy of the wormlike chain as the spacing between the walls decreases(or as the total contour length of the wormlike chain increases or as the persistence length of the chain increases)is simulated.The main reason for these changes is a degradation of the long wormlike chain into a Gaussian long chain under weak confinement. 相似文献
93.
A structurally stable, 3d-4f heterometallic coordination polymer has been solvothermally synthesised and evaluated for its accomplished materials properties. The light absorption activity in the visible band was higher for unique Ce-Fe MOF than that of the homometallic Ce-MOF or Fe- MOF. The intimate overlap of two different metal clusters in heterometallic environmental induced the formation of low line conduction orbital, which ultimately lowered the transition energy. The heterometallic acquired an additional sensitisation from a Fe-μ3-oxo cluster that had vibrantly enhanced the light uptake activity. The vacancy created in the 6s, 5d orbital of Ce in Ce-Fe MOF contributed to the photo-excitation of electrons and reduced the recombination time. This distinct intramolecular arrangement assisted the exciton trapping characteristic. Also, the presence of multiple metal cores in the framework aided to confine the increased number of excitons for a redox reaction. The solar photocatalysis study with acetaminophen revealed these improved materialistic features by degrading it 94.6% with a rate constant of 0.0137 min−1. The recycle studies confirmed the robust stability of the synthesised MOF. 相似文献
94.
Wolfgang S.M. Werner Fabian Helmberger Manuel Schürrer Christoph Eisenmenger-Sittner Olga Y. Ridzel 《Surface and interface analysis : SIA》2022,54(7):681-687
Reflection electron energy loss spectra (REELS) were measured for five insulating organic compounds: Kapton, polyethylene (PE), poly(methyl methacrylate) (PMMA), polystyrene (PS) and polytetrafluoroethylene (PTFE), as well as for Ni and Si, in the energy range between 200 and 1600 eV. The average number of surface excitations for a single surface crossing were determined from the experimental data and were found to be considerably smaller than for earlier studied materials, which mainly consisted of elemental metals [Surf. Sci. 486(2001)L461]. The surface excitation parameter, a material parameter used to quantify the relative intensity of surface losses in (photo)electron spectroscopy, was extracted from the data and compared with values found in the literature. The results indicate that surface excitations only have a minor influence on quantification of XPS spectra of polymers. On the other hand, a correction for surface excitations turns out to be essential for measurements of the electron inelastic mean free path of polymers when a metal is used as reference material. 相似文献
95.
Obtaining superhydrophobic surfaces for their application in electronics and flexible wearable devices remains a significant challenge. Most previously reported methods for obtaining superhydrophobic surfaces involve complex and expensive preparation techniques and thus cannot be used for practical applications. Ion-beam irradiation is a simple and promising method for fabricating superhydrophobic nanostructures on large areas at a low cost. Ion-beam irradiation using argon and oxygen gases was used to prepare silica nanorod structures on glass substrates. This study is not just a modification of the surface of nanoparticles, but a change in nanoparticle shape. The nanorods were subsequently treated with perfluorooctyltriethoxysilane to obtain superhydrophobicity. The surface of the silica nanorods exhibited a static water contact angle of 153°, indicating superhydrophobicity. The combination of rough structures of silica nanorods and low surface energy resulted in superhydrophobicity. The surface properties were evaluated in detail using Fourier-transform infrared spectroscopy, field-emission scanning electron microscopy, and X-ray photoelectron spectroscopy. The proposed method is facile, inexpensive, and can be used for the large-scale production of nanorod structures for potential industrial applications. 相似文献
96.
Huaizhi Gao Runnan Yu Zongwen Ma Yongshuai Gong Biao Zhao Qianglong Lv Zhan'ao Tan 《Journal of polymer science. Part A, Polymer chemistry》2022,60(6):865-916
Organometallic complexes (OMCs) consisting of organic and metal active moieties have shown immense potential for application in solar cells. The diverse structure, rich porosity, and unique charge centers of OMCs enable them to be functional in solar cells. In this review, we introduced four types of OMCs, such as crown organometallic complexes, β-diketone metal complexes, cyclometallic complexes, and main chain metal-containing polymers, providing an in-depth analysis of the structure-performance relationship. OMCs could serve as active or interlayer materials in a variety of solar cell systems such as organic solar cells, perovskite solar cells, and dye-sensitized solar cells, especially some metals to improve the photoelectric performance of the device as dopants. In the end, perspectives on the opportunities and challenges of OMCs are given. 相似文献
97.
2,3-Disubstituted Fluorene Scaffold for Efficient Green Phosphorescent Organic Light-Emitting Diodes
Jia-Jia Wei Yong-Jian Yang Dr. Xiang-Yang Liu Dr. Runlai Li Prof. Dr. Shu-an Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(39):e202200756
Fluorene is a classic three-membered polycyclic aromatic hydrocarbon, and it has been widely used in optoelectronic devices. Here we explore a simple and efficient strategy for the derivatization at the 2- and 3- positions in fluorene unit. By introducing different types of substituents, we design two pairs of 2,3-disubstituted fluorene isomers and use them as host materials for phosphorescent organic light-emitting diodes (PHOLEDs). The green PHOLEDs hosted by these fluorene derivatives realize high external quantum efficiencies (EQE) over 20 % with low efficiency roll-off. Particularly, the devices hosted by 2TRz3TPA and 2TPA3TRz achieve nearly 24 % EQE and 104 lm W−1 power efficiency. These results clearly demonstrate that the 2,3-disubstituted fluorene platforms are potentially useful for constructing host materials. 相似文献
98.
In this paper, the three-dimensional (3D) interfacial fracture is analyzed in a one-dimensional (1D) hexagonal quasicrystal (QC) coating structure under mechanical loading. A planar interface crack with arbitrary shape is studied by a displacement discontinuity method. Fundamental solutions of interfacial concentrated displacement discontinuities are obtained by the Hankel transform technique, and the corresponding boundary integral-differential equations are constructed with the superposition principle. Green’s functions of constant interfacial displacement discontinuities within a rectangular element are derived, and a boundary element method is proposed for numerical simulation. The singularity of stresses near the crack front is investigated, and the stress intensity factors (SIFs) as well as energy release rates (ERRs) are determined. Finally, relevant influencing factors on the fracture behavior are discussed. 相似文献
99.
电离能是原子和分子的重要的特性参数,在光物理和光化学过程中起着重要作用,精确电离能对相关研究具有重要意义.电离能是调试零动能光谱信号的重要参考数据,在判断异构物数量和分子构型方面也起着关键作用.1,3-二乙氧基苯是一种重要的苯的衍生物,实验证实在超声分子束中包含两种旋转异构物Ⅰ(downup)和Ⅲ(down-down).它们的精确电离能还未见文献报道.本文采用直线式飞行时间质谱仪测量了静电场中1,3-二乙氧基苯光电离效率曲线,通过不同电场强度下测量的电离能(Stark效应)对场强的平方根线性拟合给出了两种异构物Ⅰ和Ⅲ精确的电离能分别为(62419±2)cm–1和(63378±2)cm–1.相对于通常的脉冲电场加速机制和零动能光谱测量的电离能,精确度大约分别由(±10)cm–1和(±5)cm–1提高到(±2)cm–1.分析和讨论了不同方法测量的物理机制和优缺点. 相似文献
100.
Entanglement of two distinguishable atoms in a rectangular waveguide: Linear approximation with single excitation 下载免费PDF全文
《中国物理 B》2021,30(9):90307-090307
We investigate the entanglement dynamics of two distinguishable two-level systems(TLSs) characterized by energy difference δ located inside a rectangular hollow metallic waveguide of transverse dimensions a and b. The effects of energy difference δ and the inter-TLS distance on the time evolution of the concurrence of the TLSs are examined in the single excitation subspace when the energy separation of the TLS is far away from the cutoff frequencies of the transverse mode. 相似文献